Rhodium-catalyzed migrative annulation and olefination of 2-aroylpyrroles with diazoesters

Author:

Strashkov Daniil M.1ORCID,Zavyalov Kirill V.1,Sakharov Pavel A.1ORCID,Agafonova Anastasiya V.1ORCID,Rostovskii Nikolai V.1ORCID,Khlebnikov Alexander F.1ORCID,Novikov Mikhail S.1ORCID

Affiliation:

1. St. Petersburg State University, Institute of Chemistry, 7/9 Universitetskaya nab., St. Petersburg, 199034, Russia

Abstract

An unprecedented Rh2(OAc)4-catalyzed domino reaction of diazoesters with 2-aroylpyrroles involves four catalytic cycles and can be applied for the synthesis of pyrrolo[1,2-c][1,3]oxazin-1-ones and 2-(pyrrol-2-yl)cinnamate esters.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

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