The structure of a one-electron oxidized Mn(iii)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity-Reference-Cited by-同舟云学术

The structure of a one-electron oxidized Mn(iii)-bis(phenolate)dipyrrin radical complex and oxidation catalysis control via ligand-centered redox activity

Published:2016 Issue:41 Volume:45 Page:16325-16334
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Lecarme Laureline¹²³⁴,Chiang Linus⁵⁶⁷⁸,Moutet Jules¹²³⁴,Leconte Nicolas¹²³⁴,Philouze Christian¹²³⁴,Jarjayes Olivier¹²³⁴,Storr Tim⁵⁶⁷⁸,Thomas Fabrice¹²³⁴

Affiliation:

1. Département de Chimie Moléculaire – Chimie Inorganique Redox (CIRE) – UMR CNRS 5250

2. Université Grenoble Alpes

3. 38041 Grenoble cedex 9

4. France

5. Simon Fraser University

6. Department of Chemistry

7. Burnaby

8. Canada

Abstract

One electron-oxidation produces a structurally characterized Mn(iii) radical complex, which catalyzes the isomerization of epoxides in addition to the epoxidation of olefins in the presence of PhIO.

Funder

Natural Sciences and Engineering Research Council of Canada

Labex

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02163H

Reference98 articles.

1. Isolation, purification, and characterization of intermediate (iodosylbenzene)metalloporphyrin complexes from the (tetraphenylporphinato)manganese(III)-iodosylbenzene catalytic hydrocarbon functionalization system

2. Enantioselective epoxidation of unfunctionalized olefins catalyzed by salen manganese complexes