Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands-Reference-Cited by-同舟云学术

Heteroleptic Zinc Catecholate Complexes with N-Donor Ligands

Published:2023-07-01 Issue:7 Volume:49 Page:412-421
ISSN:0132-344X
Container-title:Координационная химия
language:
Short-container-title:Koordinacionnaâ himiâ

Author:

Maleeva A. V.¹,Trofimova O. Yu.¹,Yakushev I. A.²,Aysin R. R.³,Piskunov A. V.¹

Affiliation:

1. Razuvaev Institute of Organometallic Chemistry, Russian Academy of Sciences, Nizhny Novgorod, Russia

2. Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia

3. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, Moscow, Russia

Abstract

New heteroleptic zinc catecholate complexes based on 3,6-di-tert-butyl-o-benzoquinone and containing metal-coordinated N-donor ligands (2,2'-bipyridine and phenanthroline) were prepared by ligand exchange. According to X-ray diffraction data, both complexes were dimers with multiple intermolecular π–π interactions between the aromatic moieties of neighboring molecules (CCDC nos. 2222704 (I), 2222705 (II)). The electronic transmission spectra of crystalline samples of I and II and their solutions show broad absorption bands in the visible region with a maximum at about 500 nm.

Publisher

The Russian Academy of Sciences

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