Preparation of iodonium ylides: probing the fluorination of 1,3-dicarbonyl compounds with a fluoroiodane-Reference-Cited by-同舟云学术

Preparation of iodonium ylides: probing the fluorination of 1,3-dicarbonyl compounds with a fluoroiodane

Published:2015 Issue:21 Volume:5 Page:16501-16506
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Geary Gemma C.¹²³⁴,Hope Eric G.¹²³⁴,Singh Kuldip¹²³⁴,Stuart Alison M.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Leicester

3. Leicester

4. UK

Abstract

The isolated iodonium ylide has been reacted successfully with TREAT-HF, hydrochloric acid, acetic acid and p-toluenesulfonic acid to form the 2-fluoro-, 2-chloro-, 2-acetyl- and 2-tosyl-1,3-ketoesters respectively.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/RA/C4RA15733H

Reference27 articles.

1. Copper-Catalyzed [18F]Fluorination of (Mesityl)(aryl)iodonium Salts

2. Cu-Catalyzed Fluorination of Diaryliodonium Salts with KF

3. Spirocyclic hypervalent iodine(III)-mediated radiofluorination of non-activated and hindered aromatics

4. Iodonium ylides for one-step, no-carrier-added radiofluorination of electron rich arenes, exemplified with 4-(([18F]fluorophenoxy)-phenylmethyl)piperidine NET and SERT ligands

5. A Practical and Convenient Fluorination of 1,3-Dicarbonyl Compounds Using Aqueous HF in the Presence of Iodosylbenzene

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