Organocatalytic asymmetric synthesis of β,β-diaryl ketones via one-pot tandem dehydration/1,6-addition/decarboxylation transformation of β-keto acids and 4-hydroxybenzyl alcohols-Reference-Cited by-同舟云学术

Organocatalytic asymmetric synthesis of β,β-diaryl ketones via one-pot tandem dehydration/1,6-addition/decarboxylation transformation of β-keto acids and 4-hydroxybenzyl alcohols

Published:2020 Issue:61 Volume:56 Page:8687-8690
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Niu Jia-Pan¹²³⁴⁵,Nie Jing¹²³⁴⁵,Li Shen¹²³⁴⁵^ORCID,Ma Jun-An¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Tianjin Key Laboratory of Molecular Optoelectronic Sciences

3. and Tianjin Collaborative Innovation Centre of Chemical Science & Engineering

4. Tianjin University

5. Tianjin 300072

Abstract

An one-pot tandem dehydration/1,6-addition/decarboxylation transformation of β-keto acids and 4-hydroxybenzyl alcohols provides an metal-free protocol to chiral β,β-diaryl ketones.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CC/D0CC02213F

Reference57 articles.

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2. Overview on the Recent Strategies for the Enantioselective Synthesis of 1, 1-Diarylalkanes, Triarylmethanes and Related Molecules Containing the Diarylmethine Stereocenter

3. First Examples of Improved Catalytic Asymmetric C−C Bond Formation Using the Monodentate Ligand Combination Approach

4. Palladium(II)-Catalyzed 1,4-Addition of Arylboronic Acids to β-Arylenones for Enantioselective Synthesis of 4-Aryl-4H-chromenes

5. Chiral Tetrafluorobenzobarrelenes as Highly Efficient Ligands for the Rhodium-catalyzed Asymmetric 1,4-Addition of Arylboronic Acids

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