Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

Author:

Stieber S. Chantal E.123,Huguet Núria123,Kageyama Takeharu123,Jevtovikj Ivana123,Ariyananda Piyal123,Gordillo Alvaro12345,Schunk Stephan A.453,Rominger Frank6723,Hofmann Peter12367,Limbach Michael12389

Affiliation:

1. CaRLa (Catalysis Research Laboratory)

2. 69120 Heidelberg

3. Germany

4. hte Aktiengesellschaft

5. 69123 Heidelberg

6. Organisch-Chemisches Institut

7. Ruprecht-Karls-Universität Heidelberg

8. BASF SE

9. 67056 Ludwigshafen

Abstract

The first palladium catalyst for the reaction of CO2, alkenes and a base to acrylates is reported (TON up to 50).

Funder

Bundesministerium für Forschung und Technologie

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

Reference35 articles.

1. Carbon Dioxide as a Chemical Feedstock, ed. M. Aresta, Wiley-VCH, Weinheim, 2010

2. T. Ohara , T.Sato, N.Shimizu, G.Prescher, H.Schwind, O.Weiberg, K.Marten and H.Greim, Acrylic Acid and Derivates, Ullmann's Encyclopedia of Industrial Chemistry, 2011

3. Acrylates from Alkenes and CO2, the Stuff That Dreams Are Made of

4. A 1-Oxa-2-nickela-5-cyclopentanone from Ethene and Carbon Dioxide: Preparation, Structure, and Reactivity

5. Ein 1-Oxa-2-nickela-5-cyclopentanon aus Ethen und Kohlendioxid; Herstellung, Struktur und Reaktivität

同舟云学术

1.学者识别学者识别

2.学术分析学术分析

3.人才评估人才评估

"同舟云学术"是以全球学者为主线,采集、加工和组织学术论文而形成的新型学术文献查询和分析系统,可以对全球学者进行文献检索和人才价值评估。用户可以通过关注某些学科领域的顶尖人物而持续追踪该领域的学科进展和研究前沿。经过近期的数据扩容,当前同舟云学术共收录了国内外主流学术期刊6万余种,收集的期刊论文及会议论文总量共计约1.5亿篇,并以每天添加12000余篇中外论文的速度递增。我们也可以为用户提供个性化、定制化的学者数据。欢迎来电咨询!咨询电话:010-8811{复制后删除}0370

www.globalauthorid.com

TOP

Copyright © 2019-2024 北京同舟云网络信息技术有限公司
京公网安备11010802033243号  京ICP备18003416号-3