Asymmetric synthesis of enantioenriched α-allyl esters through Pd(BINAPHANE)-catalysed allylation of disubstituted ketenes-Reference-Cited by-同舟云学术

Asymmetric synthesis of enantioenriched α-allyl esters through Pd(BINAPHANE)-catalysed allylation of disubstituted ketenes

Published:2024 Issue:24 Volume:60 Page:3283-3286
ISSN:1359-7345
Container-title:Chemical Communications
language:en
Short-container-title:Chem. Commun.

Author:

Ibrahim Ahmad A.¹,O’Reilly Stephen C. J.²,Bottarel Margot²,Kerrigan Nessan J.²^ORCID

Affiliation:

1. Department of Chemistry, Oakland University, 2200 N. Squirrel Rd, Rochester, MI 48309, USA

2. School of Chemical Sciences and Life Sciences Institute, Dublin City University, Glasnevin, Dublin 9, Ireland

Abstract

A Pd2dba3·CHCl3 (2.5 mol%)-BINAPHANE (5 mol%) catalytic system promotes the enantioselective allylation of disubstituted ketenes to give α-allyl esters.

Funder

Royal Society of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/CC/D4CC00057A

Reference41 articles.

1. Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications

2. The Construction of All-Carbon Quaternary Stereocenters by Use of Pd-Catalyzed Asymmetric Allylic Alkylation Reactions in Total Synthesis

3. Transition Metal-Catalyzed Decarboxylative Allylation and Benzylation Reactions

4. Asymmetric Transition-Metal-Catalyzed Allylic Alkylations: Applications in Total Synthesis

5. Asymmetric Transition Metal-Catalyzed Allylic Alkylations

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