Charge transfer modulation in charge transfer co-crystals driven by crystal structure morphology

Author:

Solano Federica1,Inaudi Paolo1ORCID,Abollino Ornella1ORCID,Giacomino Agnese1ORCID,Chiesa Mario2ORCID,Salvadori Enrico2ORCID,Kociok-Kohn Gabriele3,da Como Enrico4ORCID,Salzillo Tommaso5ORCID,Fontanesi Claudio67ORCID

Affiliation:

1. Department of Drug Science and Technology, University of Torino, Via Giuria 9, Torino, Italy

2. Department of Chemistry, University of Torino, Via Giuria 5, Torino, Italy

3. Material and Chemical Characterization Facility (MC2), University of Bath, Claverton Down, Bath, BA2 7AY, UK

4. Department of Physics, University of Bath, BA2 7AY, UK

5. Department of Industrial Chemistry, “Toso Montanari”, University of Bologna, Viale del Risorgimento 4, Bologna, Italy

6. University of Modena and Reggio Emilia, DIEF, via Vivarelli 10, 41125, Modena, Italy

7. National Interuniversity Consortium of Materials Science and Technology (INSTM), Via G. Giusti 9, 50121, Firenze, FI, Italy

Abstract

The electronic properties of a charge-transfer semiconducting organic co-crystal, perylene: 2,3,5,6-tetrafluoro-7,7,8,8 tetracyanoquinodimethane (PE, donor (D) : F4, acceptor (A)) in its 3 : 2 stoichiometry, are experimentally and theoretically studied.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

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