Remote stereoselective deconjugation of α,β-unsaturated esters by simple amidation reactions
Author:
Affiliation:
1. Department of Organic Chemistry
2. University of Geneva
3. CH-1211 Geneva 4
4. Switzerland
5. Laboratory of Crystallography
6. Department of Physical Chemistry
Abstract
The amidation of macrocyclic conjugated esters affords in one-pot single (chiral) β,γ-unsaturated diastereomers via effective remote stereocontrol.
Funder
Swiss National Science Foundation
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC01118C
Reference51 articles.
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4. Photochemical reactions. XIV. Additions to ethyl propiolate
5. Photochemistry of .alpha.,.beta.-unsaturated esters. VI. Large deuterium solvent isotope effect on a photochemical reaction
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