<i>Pfeiffer</i> effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles-Reference-Cited by-同舟云学术

Pfeiffer effect on configurationally labile dyes within ternary complexes with metal ions and enantiopure macrocycles

Published:2024 Issue:6 Volume:53 Page:2665-2669
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Pál Dávid¹^ORCID,Lacour Jérôme¹^ORCID

Affiliation:

1. Department of Organic Chemistry, University of Geneva, Quai Ernest Ansermet 30, CH-1211 Geneva, Switzerland

Abstract

A labile helical oximate dye is used to probe complexes made of an enantiopure macrocycle and metal ions. Strong induced ECD only occurs in the presence of Na+ and K+ at 20 °C.

Funder

Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung

Université de Genève

Société Académique de Genève

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D3DT04098D

Reference38 articles.

1. Gauche Effect in 1,2-Difluoroethane. Hyperconjugation, Bent Bonds, Steric Repulsion

2. Fluorine Gauche Effect Explained by Electrostatic Polarization Instead of Hyperconjugation: An Interacting Quantum Atoms (IQA) and Relative Energy Gradient (REG) Study

3. Atroposelective transformation of axially chiral (hetero)biaryls. From desymmetrization to modern resolution strategies

4. Dissymmetric solvent interactions. Thermodynamic parameters for the enantiomerization of tris(o-phenanthroline)nickel(II) ions in (-)-2,3-butanediol

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