Aminative Umpolung cyclization for synthesis of chiral exocyclic vicinal diamines
Author:
Affiliation:
1. The Education Ministry Key Lab of Resource Chemistry and Shanghai Key Laboratory of Rare Earth Functional Materials
2. Shanghai Normal University
3. Shanghai 200234
4. P. R. China
Abstract
Chiral exocyclic vicinal trans-diamines were efficiently synthesized from aldehyde-imines via decarboxylative aminative Umpolung cyclization strategy.
Funder
National Natural Science Foundation of China
Ministry of Education of the People's Republic of China
Publisher
Royal Society of Chemistry (RSC)
Subject
Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2018/OB/C8OB02000K
Reference107 articles.
1. The Chemistry of Vicinal Diamines
2. Vicinal Diamino Functionalities as Privileged Structural Elements in Biologically Active Compounds and Exploitation of their Synthetic Chemistry
3. Chiral Tertiary Diamines in Asymmetric Synthesis
4. Metal-catalysed 1,2-diamination reactions
5. Privileged Chiral Catalysts
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