Photoredox-catalyzed regio- & stereoselective C(sp<sup>2</sup>)–H cyanoalkylation of enamides with cycloketone oximes <i>via</i> selective C–C bond cleavage/radical addition cascade-Reference-Cited by-同舟云学术

Photoredox-catalyzed regio- & stereoselective C(sp²)–H cyanoalkylation of enamides with cycloketone oximes via selective C–C bond cleavage/radical addition cascade

Published:2022 Issue:17 Volume:24 Page:6524-6530
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Guan Ting¹²,Guo Jing-Yu¹²,Zhang Qing-Hong¹,Xu Xin-Wen¹,Yu Xiao-Yu¹,Zhang Yu³^ORCID,Zhao Kai¹⁴^ORCID

Affiliation:

1. Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China

2. PharmaBlock Sciences (Nanjing), Inc, 10 Xuefu Road, Jiangbei New Area, Nanjing, 210032, China

3. College of Chemical Engineering, Nanjing Forestry University, Nanjing 210037, China

4. Guangdong Provincial Key Laboratory of Catalysis, Southern University of Science and Technology, Shenzhen 518055, China

Abstract

A visible-light-induced regio- and stereoselective C(sp2)–H coupling reaction of enamides with cycloketone oximes is developed under mild and environmentally-friendly conditions.

Funder

Natural Science Research of Jiangsu Higher Education Institutions of China

Guangdong Provincial Key Laboratory Of Catalysis

Nanjing Tech University

Soochow University

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Pollution,Environmental Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/GC/D2GC01978G