Through-space π-delocalization in a conjugated macrocycle consisting of [2.2]paracyclophane

Author:

Wu Yayu12345,Zhuang Guilin678ORCID,Cui Shengsheng12345,Zhou Yu12345,Wang Jinyi12345,Huang Qiang12345,Du Pingwu12345ORCID

Affiliation:

1. Hefei National Laboratory of Physical Science at the Microscale

2. CAS Key Laboratory of Materials for Energy Conversion

3. Department of Materials Science and Engineering

4. iChEM (Collaborative Innovation Center of Chemistry for Energy Materials)

5. University of Science and Technology of China

6. College of Chemical Engineering, Zhejiang University of Technology

7. Hangzhou

8. China

Abstract

Herein, we report the synthesis and characterization of a [2.2]paracyclophane-containing macrocycle (PCMC) as a new through-space conjugated macrocycle using only benzene groups as the skeleton.

Funder

National Natural Science Foundation of China

National Basic Research Program of China

Natural Science Foundation of Zhejiang Province

National Synchrotron Radiation Laboratory

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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