Iridium(<scp>iii</scp>)-catalyzed one-pot synthesis of planar chiral emissive materials through C

Iridium(iii)-catalyzed one-pot synthesis of planar chiral emissive materials through C–H activation

Published:2024 Issue:12 Volume:11 Page:3384-3390
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Liu Wenjing¹,Ji Honghan¹²³,Duan Wenzeng¹^ORCID,Wang Huaiwei¹^ORCID,Huo Yanmin¹,Huang Xianqiang¹^ORCID,Duan Pengfei²³^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering, Shandong Provincial Key Laboratory of Chemical Energy Storage and Novel Cell Technology, Liaocheng University, Liaocheng 252000, China

2. CAS Key Laboratory of Nanosystem and Hierarchical Fabrication National Center for Nanoscience and Technology (NCNST) No.11, ZhongGuanCun BeiYiTiao, Beijing 100190, China

3. University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

Pioneering the synthesis of 4-aryl-5-carboxy[2.2]paracyclophanes through C(sp2)–H activation, we constructed distinct small organic molecules possessing circularly polarized luminescence (CPL) with high quantum yields of up to 0.42.

Funder

Natural Science Foundation of Shandong Province

National Natural Science Foundation of China

Natural Science Foundation of Beijing Municipality

Dream Project of Ministry of Science and Technology of the People's Republic of China

Chinese Academy of Sciences

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/QO/D4QO00582A

Reference44 articles.

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2. Planar chiral [2.2]paracyclophanes: from synthetic curiosity to applications in asymmetric synthesis and materials

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5. [2.2]Paracyclophane-Based Chiral Platforms for Circularly Polarized Luminescence Fluorophores and Their Chiroptical Properties: Past and Future