Command-destruct thermosets via photoinduced thiol-catalyzed β-scission of acyclic benzylidene acetals-Reference-Cited by-同舟云学术

Command-destruct thermosets via photoinduced thiol-catalyzed β-scission of acyclic benzylidene acetals

Published:2020 Issue:43 Volume:11 Page:6873-6878
ISSN:1759-9954
Container-title:Polymer Chemistry
language:en
Short-container-title:Polym. Chem.

Author:

Walker William D.¹²³⁴^ORCID,Sandoz Michael J.¹²³⁴,Roland Samuel¹²³⁴,Buster Tony M.¹²³⁴,Newman John K.⁵⁶⁷⁴,Patton Derek L.¹²³⁴^ORCID

Affiliation:

1. School of Polymer Science and Engineering

2. University of Southern Mississippi

3. Hattiesburg

4. USA

5. US Army

6. Engineering Research & Development Center

7. Vicksburg

Abstract

Photoinduced thiol-catalyzed hydrogen abstraction and β-scission of acyclic benzylidene acetals is demonstrated as a new route to “command-destruct” polymer thermosets.

Funder

National Science Foundation

Engineer Research and Development Center

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Polymers and Plastics,Biochemistry,Bioengineering

Link

http://pubs.rsc.org/en/content/articlepdf/2020/PY/D0PY01006E

Reference28 articles.

1. Thiyl Radicals in Organic Synthesis

2. Thiol-Ene Click Chemistry

3. The power of thiol-ene chemistry

4. Y. Luo , Handbook of Bond Dissociation Energies in Organic Compounds , CRC Press , Boca Raton, FL , 2003

5. Thiol-enes: Chemistry of the past with promise for the future

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