Stepwise cyclopalladation of 2-phenacylthiopyridine to give C,C,N-pincer complexes
Author:
Affiliation:
1. Grupo de Química Organometálica
2. Departamento de Química Inorgánica
3. Facultad de Química
4. Universidad de Murcia
5. 30071 Murcia, Spain
6. SAI
Abstract
The synthesis of a family of palladium C,C,N-pincer complexes derived from 2-phenacylthiopyridine, obtained by an unprecedented stepwise double cyclopalladation process, is reported. The pincer moiety behaves as a metallaligand.
Publisher
Royal Society of Chemistry (RSC)
Subject
Inorganic Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2014/DT/C4DT02085E
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