Efficient and stereoselective synthesis of monomeric and bimetallic pincer complexes containing Pd-bonded stereogenic carbons-Reference-Cited by-同舟云学术

Efficient and stereoselective synthesis of monomeric and bimetallic pincer complexes containing Pd-bonded stereogenic carbons

Published:2016 Issue:79 Volume:6 Page:75951-75959
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Tay Wee Shan¹²³⁴,Yang Xiang-Yuan¹²³⁴,Li Yongxin¹²³⁴,Pullarkat Sumod A.¹²³⁴,Leung Pak-Hing¹²³⁴

Affiliation:

1. Division of Chemistry & Biological Chemistry

2. School of Physical and Mathematical Sciences

3. Nanyang Technological University

4. Singapore 637371

Abstract

Optically-pure aliphatic N–C(sp³)–E Pd pincer complexes with C-stereogenic centers were synthesized via stepwise (1) enantioselective catalytic hydrophosphination, (2) P(iii) → P(v) oxidation and (3) diastereoselective C(sp³)–H activation.

Funder

Ministry of Education - Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/RA/C6RA16721G

Reference57 articles.

1. Transition metal–carbon bonds. Part XLII. Complexes of nickel, palladium, platinum, rhodium and iridium with the tridentate ligand 2,6-bis[(di-t-butylphosphino)methyl]phenyl

2. A novel type of Pt–C interaction and a model for the final stage in reductive elimination processes involving C–C coupling at Pt; synthesis and molecular geometry of [1,N,N′-η-2,6-bis{(dimethylamino)methyl}-toluene]iodoplatinum(II) tetrafluoroborate

3. Cyclometalated Phosphine-Based Pincer Complexes: Mechanistic Insight in Catalysis, Coordination, and Bond Activation

4. Pincer Complexes as Catalysts in Organic Chemistry

5. Catalysis by Palladium Pincer Complexes

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