Direct synthesis of tetraalkoxysilanes in a high-pressure mechanochemical reactor-Reference-Cited by-同舟云学术

Direct synthesis of tetraalkoxysilanes in a high-pressure mechanochemical reactor

Published:2022 Issue: Volume: Page:
ISSN:2058-9883
Container-title:Reaction Chemistry & Engineering
language:en
Short-container-title:React. Chem. Eng.

Author:

Krizhanovskiy Ilya N.¹,Temnikov Maxim N.¹^ORCID,Anisimov Anton A.¹^ORCID,Ratnikov Andrey K.¹²,Levin Ivan S.³^ORCID,Naumkin Alexander V.¹^ORCID,Chistovalov Sergey M.¹,Muzafarov Aziz M.¹⁴^ORCID

Affiliation:

1. A.N. Nesmeyanov Institute of Organoelement Compounds of Russian Academy of Sciences (INEOS RAS) Russia, Vavilova St. 28, Moscow, Russian Federation

2. Mendeleev University of Chemical Technology, 9 Miusskaya ploshchad', 125047 Moscow, Russia

3. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, 29 Leninskii Prosp., 119991 Moscow, Russia

4. Enikolopov Institute of Synthetic Polymeric Materials Russian Academy of Sciences, Moscow, Russia

Abstract

A high-pressure mechanochemical reactor was used for selective and solvent free conversion of gross technical grade silicon to tetraalkoxysilanes. This technique provided high silicon conversions and unprecedented low reaction temperature.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

Fluid Flow and Transfer Processes,Process Chemistry and Technology,Chemical Engineering (miscellaneous),Chemistry (miscellaneous),Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2022/RE/D1RE00522G

Reference23 articles.

1. D. E.Katsoulis , R. G.Schmidt and G. A.Zank , in Organosilicon Compounds , Elsevier , 2017 , pp. 301–322

2. Dimethyldichlorosilane and the Direct Synthesis of Methylchlorosilanes. The Key to the Silicones Industry

3. Organoelement chemistry: promising growth areas and challenges