From silicon to silicones without dimethyldichlorosilane: direct green mechanochemical synthesis of methylmethoxysilanes from silicon and dimethyl ether-Reference-Cited by-同舟云学术

From silicon to silicones without dimethyldichlorosilane: direct green mechanochemical synthesis of methylmethoxysilanes from silicon and dimethyl ether

Published:2024 Issue:11 Volume:26 Page:6656-6665
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Kryzhanovskii I. N.¹,Temnikov M. N.¹^ORCID,Anisimov A. A.¹^ORCID,Ratnikov A. K.¹,Frank I. V.¹,Naumkin A. V.¹^ORCID,Chistovalov S. M.¹,Muzafarov A. M.¹²

Affiliation:

1. A. N. Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, 119334, Moscow, Russia

2. Enikolopov Institute of Synthetic Polymeric Materials, Russian Academy of Sciences, 117393, Moscow, Russia

Abstract

First gram-scale synthesis of methylmethoxysilanes via mechanochemical direct reaction of Si with dimethyl ether, achieving nearly 100% silicon conversion and high selectivity for dimethylsilyl-containing products.

Funder

Russian Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D4GC00472H

Reference53 articles.

1. E. G.Rochow , Silicon and Silicones , Springer Berlin Heidelberg , 1987

2. Industrial synthesis of reactive silicones: reaction mechanisms and processes

3. J. E.Mark , M. P.Wolf , G. B.Salieb-Beugelaar , P.Hunziker , D. E.Katsoulis , R. G.Schmidt and G. A.Zank , in Siloxanes and Silicones (Advances in Silicone Technologies 2000–15), Organosilicon Compounds , ed. V. Ya. Lee , Elsevier Ltd , Washington DC , 2018 , vol. 83 , pp. 97–134

4. C.Corden , D.Tyrer , H.Menadue , J.Calero , J.Dade and R.Leferink , Global Silicones Council Socio-economic evaluation of the global silicones industry Final Report , 2016

5. RTV silicone elastomers in hand prosthetics