Affiliation:
1. Department of Theoretical Chemistry, Amsterdam Institute of Molecfular and Life Sciences (AIMMS), Amsterdam Center for Multiscale Modeling (ACMM), Vrije Universiteit Amsterdam, De Boelelaan 1083, Amsterdam 1081 HV, The Netherlands
Abstract
Tropone can be activated in Diels–Alder reactionsviacarbonyl umpolung. The enhanced reactivity of tropone originates from the increased asynchronicity of the reaction and not by the, recently proposed, induced antiaromaticity.
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Cited by
3 articles.
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