Optimization of crystal packing in semiconducting spin-crossover materials with fractionally charged TCNQδ− anions (0 < δ

Optimization of crystal packing in semiconducting spin-crossover materials with fractionally charged TCNQδ− anions (0 < δ < 1)

Published:2021 Issue:32 Volume:12 Page:10765-10779
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Üngör Ökten¹^ORCID,Choi Eun Sang²,Shatruk Michael¹²^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, 95 Chieftan Way, Tallahassee, FL 32306, USA

2. National High Magnetic Field Laboratory, 1800 E Paul Dirac Dr, Tallahassee, FL 32310, USA

Abstract

Co-crystallization of the cationic complex [Fe(3-bpp)2]2+ with fractionally charged TCNQδ− anions (0 < δ < 1) affords semiconducting spin-crossover (SCO) materials. The abruptness of SCO is strongly dependent on the interstitial solvent content.

Funder

Division of Chemistry

National Science Foundation

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D1SC02843J

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