Light-induced spin-state switching in Fe(<scp>ii</scp>) spin-crossover complexes with thiazole-based chelating ligands-Reference-Cited by-同舟云学术

Light-induced spin-state switching in Fe(ii) spin-crossover complexes with thiazole-based chelating ligands

Published:2024 Issue:25 Volume:53 Page:10511-10520
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Jo Minyoung¹,Amanyazova Botagoz¹²^ORCID,Yergeshbayeva Sandugash¹,Gakiya-Teruya Miguel¹,Üngör Ökten¹,Lopez Rivera Paola¹³,Jen Natalie¹^ORCID,Lukyanenko Evgeny⁴,Kurkin Alexander V.⁴^ORCID,Erkasov Rakhmetulla²^ORCID,Meisel Mark W.⁵^ORCID,Hauser Andreas⁶,Chakraborty Pradip⁷^ORCID,Shatruk Michael¹^ORCID

Affiliation:

1. Department of Chemistry and Biochemistry, Florida State University, Tallahassee, Florida 32306, USA

2. Department of Chemistry, L.N. Gumilyov Eurasian National University, Astana 010008, Kazakhstan

3. Department of Chemistry, University of Puerto Rico at Humacao, Humacao, PR 00792, Puerto Rico

4. Department of Chemistry, Lomonosov Moscow State University, Moscow, 119234, Russia

5. Department of Physics and National High Magnetic Field Laboratory, University of Florida, Gainesville, Florida 32611, USA

6. Department of Physical Chemistry, University of Geneva, CH-1211, Geneva 4, Switzerland

7. Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India

Abstract

Three homoleptic Fe(ii) complexes with bidentate thiazole-based ligands exhibit spin-crossover (SCO) at the metal center. Abrupt temperature-driven and light-induced spin transitions are observed due to cooperative interactions between SCO cations.

Funder

Division of Materials Research

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/DT/D4DT00308J

Reference30 articles.

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4. Coordination of 2,2'-Biimidazole with Iron, Cobalt, Nickel and Copper

5. Iron(II) and Nickel(II) Complexes of 4,4′-Bithiazole: Spectral, Magnetic and Structural Studies