Nazarov cyclization of dienylaziridines: synthesis of cyclopentadienyl/hydrinedienyl/indenyl glycines

Author:

Sudhakar Gangarajula12345,Reddy Karla Janardhan12345,Nanubolu Jagadesh Babu674

Affiliation:

1. Division of CPC (Organic Chemistry-II)

2. CSIR-Indian Institute of Chemical Technology

3. Hyderabad-500007

4. India

5. Academy of Scientific and Innovative Research

6. Center for X-Ray Crystallography

7. CSIR-IICT

Abstract

Cyclopentadienyl, hydrinedienyl, and indenyl glycines were synthesized by the Nazarov cyclization of dienylaziridines for the first time. Several substrates were synthesized to demonstrate the compatibility of this reaction. Asymmetric synthesis of these amino acids was also developed to show the additional scope of this method.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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