Synthesis of novel chiral heterometallic terpene oximates: unusual generation of an aluminium enolate by a cooperative effect-Reference-Cited by-同舟云学术

Synthesis of novel chiral heterometallic terpene oximates: unusual generation of an aluminium enolate by a cooperative effect

Published:2016 Issue:26 Volume:45 Page:10514-10518
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Fernández-Millán María¹²³⁴⁵,Temprado Manuel⁶²³⁴⁵,Cano Jesús¹²³⁴⁵,Cuenca Tomás¹²³⁴⁵,Mosquera Marta E. G.¹²³⁴⁵

Affiliation:

1. Inorganic Chemistry Department

2. University of Alcala

3. Campus Universitario

4. Alcalá de Henares

5. Spain

6. Physical Chemistry Department

Abstract

Al–K heterometallic oximate derivatives react with aryl ketones leading to heterometallic enolates via a cooperative mechanism where the oximate ligand has a prominent role, as confirmed by DFT calculations.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2016/DT/C6DT02116F

Reference37 articles.

1. Controlled Polymerization of Next-Generation Renewable Monomers and Beyond

2. A. J. D. Silvestre and A.Gandini, in Monomers, Polymers and Composites from Renewable Resources, ed. M. N. Belgacem and A. Gandini, Elsevier, 2008, pp. 17–38

3. Myrcene as a Natural Base Chemical in Sustainable Chemistry: A Critical Review

4. Vapor Phase Thermal Isomerization of α- and β-Pinene*

5. M. Eggersdorfer , Terpenes in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH Verlag GmbH & Co., New York, 2000

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