Alkali metal⋯methyl short contacts in aluminates: more than agostic interactions-Reference-Cited by-同舟云学术

Alkali metal⋯methyl short contacts in aluminates: more than agostic interactions

Published:2023 Issue: Volume: Page:
ISSN:1359-6640
Container-title:Faraday Discussions
language:en
Short-container-title:Faraday Discuss.

Author:

Damián Jesús¹^ORCID,Rentero Christian¹^ORCID,Echeverría Jorge²^ORCID,Mosquera Marta E. G.¹^ORCID

Affiliation:

1. Department of Organic and Inorganic Chemistry, Institute of Chemical Research “Andrés M. del Río” (IQAR), Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Madrid, Spain

2. Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain

Abstract

Short contacts between alkali metal cations and methyl groups in aluminates, traditionally considered agostic interactions, can be rationalized in terms of an electron-rich carbon atom and its interaction with the cation.

Funder

Comunidad de Madrid

Gobierno de Aragón

Ministerio de Ciencia e Innovación

Agencia Estatal de Investigación

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/FD/D2FD00144F

Reference41 articles.

1. Deprotonative Metalation Using Ate Compounds: Synergy, Synthesis, and Structure Building

2. Introducing Deep Eutectic Solvents to Polar Organometallic Chemistry: Chemoselective Addition of Organolithium and Grignard Reagents to Ketones in Air

3. Mixed Alkylamido Aluminate as a Kinetically Controlled Base

4. Lithium diamidodihydridoaluminates: bimetallic cooperativity in catalytic hydroboration and metallation applications

5. N,N,O-Tridentate Mixed Lithium–Magnesium and Lithium–Aluminum Complexes: Synthesis, Characterization, and Catalytic Activities

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