Structure and thermal expansion of the tungsten bronze Pb2KNb5O15-Reference-Cited by-同舟云学术

Structure and thermal expansion of the tungsten bronze Pb2KNb5O15

Published:2014 Issue:19 Volume:43 Page:7037-7043
ISSN:1477-9226
Container-title:Dalton Trans.
language:en
Short-container-title:Dalton Trans.

Author:

Lin Kun¹²³,Wu Hui⁴⁵⁶⁷⁸,Wang Fangfang¹²³,Rong Yangchun¹²³,Chen Jun¹²³,Deng Jinxia¹²³⁹²,Yu Ranbo¹²³,Fang Liang¹⁰¹¹¹²¹³,Huang Qingzhen⁴⁵⁶,Xing Xianran¹²³

Affiliation:

1. Department of Physical Chemistry

2. University of Science and Technology Beijing

3. Beijing 100083, China

4. NIST Center for Neutron Research

5. National Institute of Standards and Technology

6. Gaithersburg, USA

7. Department of Materials Science and Engineering

8. University of Maryland

9. Department of Chemistry

10. Key Laboratory of New Processing Technology for Nonferrous Metals and Materials

11. Ministry of Education

12. Guilin University of Technology

13. Guilin 541004, China

Abstract

Negative thermal expansion and abnormal spontaneous polarization direction along b axis in tetragonal tungsten bronze Pb₂KNb₅O₁₅ are presented. A Pb–O covalency, octahedrons cooperative rotation mechanism is proposed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2014/DT/C3DT53340A

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