Large nonlinear optical effect in tungsten bronze structures via Li/Na cross-substitutions

Author:

Chu Shihang12345,Lin Kun12345ORCID,Yang Tao12345,Yu Chengyi12345,Cao Yili12345,Zhang Yujuan12345,Sun Yujiao12345,Li Zerui12345,Jiang Xingxing6789,Lin Zheshuai6789ORCID,Li Qiang12345,Chen Jun12345ORCID,Kato Kenichi6789,Wu Hui101112ORCID,Huang Qingzhen101112,Xing Xianran12345ORCID

Affiliation:

1. Beijing Advanced Innovation Center for Materials Genome Engineering

2. Institute of Solid State Chemistry

3. Department of Physical Chemistry

4. University of Science and Technology Beijing

5. Beijing 100083

6. Technical Institute of Physics and Chemistry

7. Chinese Academy of Sciences

8. Beijing 100190

9. China

10. Center for Neutron Research, National Institute of Standards and Technology

11. Gaithersburg

12. USA

Abstract

By a simple cross-substitution of Li/Na in a tungsten bronze structures, the SHG response was significantly prompted to ∼47 × KDP, manifesting local distortion be a possibly general route to improve NLO effect in stiff and low symmetric structures.

Funder

National Natural Science Foundation of China

Fundamental Research Funds for the Central Universities

University of Science and Technology Beijing

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis

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