Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants-Reference-Cited by-同舟云学术

Isolation of +2 rare earth metal ions with three anionic carbocyclic rings: bimetallic bis(cyclopentadienyl) reduced arene complexes of La2+ and Ce2+ are four electron reductants

Published:2015 Issue:12 Volume:6 Page:7267-7273
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Kotyk Christopher M.¹²³⁴,Fieser Megan E.¹²³⁴,Palumbo Chad T.¹²³⁴,Ziller Joseph W.¹²³⁴,Darago Lucy E.¹²⁵⁴,Long Jeffrey R.¹²⁵⁴,Furche Filipp¹²³⁴,Evans William J.¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of California

3. Irvine

4. USA

5. Berkeley

Abstract

A new option for stabilizing unusual Ln²⁺ ions has been identified in the reaction of (C₅H₄SiMe₃)₃Ln (Ln = La, Ce) with potassium graphite and 2.2.2-cryptand in benzene.

Funder

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/SC/C5SC02486B

Reference38 articles.

1. Lanthanum Does Form Stable Molecular Compounds in the +2 Oxidation State

2. Synthesis of a Crystalline Molecular Complex of Y2+, [(18-crown-6)K][(C5H4SiMe3)3Y]

3. Completing the Series of +2 Ions for the Lanthanide Elements: Synthesis of Molecular Complexes of Pr2+, Gd2+, Tb2+, and Lu2+

4. Structural, Spectroscopic, and Theoretical Comparison of Traditional vs Recently Discovered Ln2+ Ions in the [K(2.2.2-cryptand)][(C5H4SiMe3)3Ln] Complexes: The Variable Nature of Dy2+ and Nd2+

5. Expanding Rare-Earth Oxidation State Chemistry to Molecular Complexes of Holmium(II) and Erbium(II)

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