Neutral inverse-sandwich rare-earth metal complexes of the benzene tetraanion

Author:

Wang Yi1ORCID,Zhang Yurou1,Liang Jiefeng1ORCID,Tan Bowen1,Deng Chong1ORCID,Huang Wenliang1ORCID

Affiliation:

1. Beijing National Laboratory for Molecular Sciences, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, P. R. China

Abstract

Neutral inverse-sandwich rare-earth metal complexes of the parent benzene tetraanion with an [M3+–(C6H6)4−–M3+] core electronic structure were synthesized and characterized. They behave as a four-electron reductant to reduce unsaturated substrates.

Funder

National Natural Science Foundation of China

Beijing National Laboratory for Molecular Sciences

Peking University

Publisher

Royal Society of Chemistry (RSC)

Reference79 articles.

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3. G. O.Spessard and G. L.Miessler , Organometallic Chemistry , Oxford University Press , Oxford , 3rd edn, 2015

4. Bis(benzene)chromium Is a δ-Bonded Molecule and Ferrocene Is a π-Bonded Molecule

5. E. P.Kündig , Transition Metal Arene π-Complexes in Organic Synthesis and Catalysis , Springer , Berlin, Heidelberg , 2004

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