Selective B–B bond activation in an unsymmetrical diborane(4) by [(Me3P)4Rh–X] (X = Me, OtBu): a switch of mechanism?-Reference-Cited by-同舟云学术

Selective B–B bond activation in an unsymmetrical diborane(4) by [(Me3P)4Rh–X] (X = Me, OtBu): a switch of mechanism?

Published:2015 Issue:18 Volume:44 Page:8600-8604
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Borner C.¹²³,Brandhorst K.¹²³^ORCID,Kleeberg C.¹²³

Affiliation:

1. Technische Universität Carolo-Wilhelmina zu Braunschweig

2. 38106 Braunschweig

3. Germany

Abstract

The unsymmetrical diborane(4) pinB–B((MeN)₂(C₆H₄)) reacts with [(Me₃P)₄Rh–X] (X = Me, OtBu) giving predominantly either [(Me₃P)₄Rh–Bpin] or [(Me₃P)₃Rh–B((MeN)₂(C₆H₄))] depending on X. At low temperatures in the presence of excess PMe₃ the unprecedented equatorial boryl complex [(Me₃P)₄Rh–B((MeN)₂(C₆H₄))] is formed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT00618J

Reference34 articles.

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