N–H deprotonation of a diaminodialkoxido diborane(4) – a structural study on bifunctional Lewis acids/bases and their dimerisation to B(sp2)2B(sp3)2N2 six membered rings-Reference-Cited by-同舟云学术

N–H deprotonation of a diaminodialkoxido diborane(4) – a structural study on bifunctional Lewis acids/bases and their dimerisation to B(sp2)2B(sp3)2N2 six membered rings

Published:2021 Issue:37 Volume:50 Page:13149-13157
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Drescher Wiebke¹,Kleeberg Christian¹^ORCID

Affiliation:

1. Institut für Anorganische und Analytische Chemie, Technische Universität Carolo-Wilhelmina zu Braunschweig, Hagenring 30, 38106 Braunschweig, Germany

Abstract

The N–H deprotonation of the diaminodialkoxido diborane(4) pinB–Bdab (1) (pin: (OCMe2)2, dab: 1,2-(NH)2C6H4), is crucial for the electrophilic N-functionalisation towards unsymmetrical diborane(4) reagents.

Funder

Deutsche Forschungsgemeinschaft

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/DT/D1DT02327F

Reference26 articles.

1. Differentially Protected Diboron for Regioselective Diboration of Alkynes: Internal-Selective Cross-Coupling of 1-Alkene-1,2-diboronic Acid Derivatives

2. sp2−sp3 Hybridized Mixed Diboron: Synthesis, Characterization, and Copper-Catalyzed β-Boration of α,β-Unsaturated Conjugated Compounds

3. Facile scission of isonitrile carbon–nitrogen triple bond using a diborane(4) reagent

4. Diboron(4) Compounds: From Structural Curiosity to Synthetic Workhorse

5. Copper‐Catalyzed B(dan)‐Installing Allylic Borylation of Allylic Phosphates

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