Cu-catalyzed debrominative cyanation of gem-dibromoolefins: a facile access to α,β-unsaturated nitriles

Author:

Ahuja Brij Bhushan1234,Sudalai Arumugam1234

Affiliation:

1. National Chemical Laboratory

2. Chemical Engineering & Process Development Division

3. Pune 411008

4. India

Abstract

An efficient catalytic route for the synthesis of α,β-unsaturated nitriles from easily accessible gem-dibromoolefins has been developed.

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference47 articles.

1. A. J. Fatiadi , in Preparation and Synthetic Applications of Cyano Compounds, ed. S. Patai and Z. Rappaport, Wiley, New York, 1983

2. Designer Magnets Containing Cyanides and Nitriles

3. Direct conversion of α,β-unsaturated nitriles into cyanohydrins using Mn(dpm)3 catalyst, dioxygen and phenylsilane

4. R. C. Larock , Comprehensive Organic Transformations, 1989, pp. 819–995

5. C. Grundmann , Houben-Weyl: Methodender Organischen Chemie. Falbe, 1985, vol. 5, pp. 1313–1527

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