Polaron self-localization in white-light emitting hybrid perovskites

Author:

Cortecchia Daniele12345,Yin Jun67284,Bruno Annalisa592104,Lo Shu-Zee Alencious67284,Gurzadyan Gagik G.67284,Mhaisalkar Subodh592104,Brédas Jean-Luc1112131415,Soci Cesare67284

Affiliation:

1. Interdisciplinary Graduate School

2. Nanyang Technological University

3. Singapore 639798

4. Singapore

5. Energy Research Institute @ NTU (ERI@N)

6. Division of Physics and Applied Physics

7. School of Physical and Mathematical Sciences

8. Singapore 637371

9. Research Techno Plaza

10. Singapore 637553

11. Laboratory for Computational and Theoretical Chemistry and Advanced Materials

12. Division of Physical Science and Engineering

13. King Abdullah University of Science and Technology

14. Thuwal 23955-6900

15. Saudi Arabia

Abstract

Ultra-broadband photoluminescence in two-dimensional (2D) perovskites (EDBE)PbX4 (where X = Cl, Br) is shown to originate from self-trapped polaronic excitons localised at specific inorganic lattice sites.

Funder

National Research Foundation-Prime Minister's office, Republic of Singapore

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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