Catalyst-free aerobic photooxidation of sensitive benzylic alcohols with chemoselectivity controlled using DMSO as the solvent-Reference-Cited by-同舟云学术

Catalyst-free aerobic photooxidation of sensitive benzylic alcohols with chemoselectivity controlled using DMSO as the solvent

Published:2024 Issue:8 Volume:26 Page:4880-4887
ISSN:1463-9262
Container-title:Green Chemistry
language:en
Short-container-title:Green Chem.

Author:

Weisheitelová Ivana¹^ORCID,Varma Naisargi²^ORCID,Chudoba Josef³,Burdziński Gotard⁴,Sikorski Marek²^ORCID,Cibulka Radek¹^ORCID

Affiliation:

1. Department of Organic Chemistry, University of Chemistry and Technology, Prague, 16628 Prague, Czech Republic

2. Faculty of Chemistry, Adam Mickiewicz University, 61-614 Poznań, Poland

3. Central Laboratories, University of Chemistry and Technology, Prague, 16628 Prague, Czech Republic

4. Faculty of Physics, Adam Mickiewicz University, 61-614 Poznań, Poland

Abstract

Irradiation of a solution of an unsaturated benzyl alcohol in DMSO under oxygen leads to ketone formation. Side-oxidations are minimized, thanks to the protective role of the DMSO solvent against singlet oxygen. No catalyst or additives are required.

Funder

Grantová Agentura České Republiky

Narodowe Centrum Nauki

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/GC/D4GC00087K

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