Anion control of tautomeric equilibria: Fe–H vs. N–H influenced by NH⋯F hydrogen bonding
Author:
Affiliation:
1. Center for Molecular Electrocatalysis
2. Pacific Northwest National Laboratory
3. Richland
4. USA
Abstract
Addition of excess BF4− to the iron hydride [Fe(PEtNMePEt)(CO)3H]+[B(C6F5)4]− leads to the NH tautomer, due to NH⋯F hydrogen bonding.
Funder
Basic Energy Sciences
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2019/SC/C8SC04239J
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