Rational design and organocatalytic enantioselective [1 + 4]-annulations of MBH carbonates with modified enones-Reference-Cited by-同舟云学术

Rational design and organocatalytic enantioselective [1 + 4]-annulations of MBH carbonates with modified enones

Published:2023 Issue:1 Volume:10 Page:150-156
ISSN:2052-4129
Container-title:Organic Chemistry Frontiers
language:en
Short-container-title:Org. Chem. Front.

Author:

Guo Xing¹²,Shen Boming¹,Liu Chang¹,Zhao Hongyue¹,Li Xuechen²^ORCID,Yu Peiyuan¹^ORCID,Li Pengfei¹^ORCID

Affiliation:

1. Shenzhen Grubbs Institute and Department of Chemistry, Guangdong Provincial Key Laboratory of Catalysis, College of Science, Southern University of Science and Technology (SUSTech), Shenzhen, Guangdong, 518055, China

2. Department of Chemistry, State Key Lab of Synthetic Chemistry, The University of Hong Kong, Hong Kong, China

Abstract

According to the frontier molecular orbital theory, two types of modified enones have been designed and successfully applied in the chiral phosphine-catalyzed stereoselective [1 + 4]-annulation of MBH carbonates for the first time.

Funder

Guangdong Provincial Key Laboratory Of Catalysis

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2023/QO/D2QO01670B

Reference28 articles.

1. A Catalytic Carbon–Phosphorus Ylide Reaction: Phosphane-Catalyzed Annulation of Allylic Compounds with Electron-Deficient Alkenes

2. Phosphine-triggered synthesis of functionalized cyclic compounds