DABCO-catalyzed mono- and bisallylation of β,γ-unsaturated ketones with Morita–Baylis–Hillman carbonates-Reference-Cited by-同舟云学术

DABCO-catalyzed mono- and bisallylation of β,γ-unsaturated ketones with Morita–Baylis–Hillman carbonates

Published:2024 Issue:35 Volume:48 Page:15446-15451
ISSN:1144-0546
Container-title:New Journal of Chemistry
language:en
Short-container-title:New J. Chem.

Author:

Yue Guizhou¹²^ORCID,Du Biao³,Wang Qiumi¹,Cheng Silu¹,Ma Lan¹,Lu Cuifen²^ORCID,Feng Juhua¹^ORCID,Hu Haipeng¹,Li Sicheng¹⁴,He Qiao¹⁵

Affiliation:

1. College of Science, Sichuan Agricultural University, Ya’an, Sichuan, 625014, China

2. Hubei Collaborative Innovation Center for Advanced Organochemical Materials & Ministry-of-Education Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Hubei University, Wuhan, Hubei, 430062, China

3. Chengdu EASTON Biopharmaceuticals Co., Ltd., Chengdu, Sichuan, 611731, China

4. The Yingjing County Emergency Management Agency, Ya’an, Sichuan, 625200, China

5. Agriculture and Rural Bureau of Daying Country, Suining, Sichuan, 629300, China

Abstract

Mono- and bisallylation of β,γ-unsaturated ketones with MBH carbonates in the presence of DABCO at rt, offered α-2-alkoxycarbonyl, α,α-di(2-alkoxycarbonyl) and α,γ-di(2-alkoxycarbonyl) α,β-unsaturated ketones in the moderate to excellent yields.

Funder

Key Laboratory for the Synthesis and Application of Organic Functional Molecules, Ministry of Education

Sichuan Provincial Science and Technology Support Program

National Key Research and Development Program of China

Publisher

Royal Society of Chemistry (RSC)

Link

http://pubs.rsc.org/en/content/articlepdf/2024/NJ/D4NJ02086C

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