Valorizing natural-abundant glucose to lactic acid using a MOF-808 catalyst under green hydrothermal conditions

Author:

Boonmark Sininat1ORCID,Ponchai Panyapat1ORCID,Adpakpang Kanyaporn1ORCID,Wannapaiboon Suttipong2ORCID,Thongratkaew Sutarat3,Faungnawakij Kajornsak3ORCID,Bureekaew Sareeya1ORCID

Affiliation:

1. School of Energy Science and Engineering, Vidyasirimedhi Institute of Science and Technology, 555 Moo 1 Payupnai, Wangchan, Rayong 21210, Thailand

2. Synchrotron Light Research Institute, 111 University Avenue, Muang, Nakhon Ratchasima 30000, Thailand

3. National Nanotechnology Center (NANOTEC), National Science and Technology Development Agency (NSTDA), 111 Thailand Science Park, Pahonyothin Rd., Klong Luang Pathumthani 12120, Thailand

Abstract

We demonstrated that a highly robust Zr-based MOF-808, owning abundant Lewis acid Zr sites and hydroxy ions, can efficiently convert glucose to lactic acid via [3+3] C–C bond cleavage, achieving a high yield of up to 77% under hydrothermal condition.

Funder

National Research Council of Thailand

Publisher

Royal Society of Chemistry (RSC)

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