Topological analysis and control of post-synthetic metalation sites in Zr-based metal–organic frameworks

Author:

Gimeno-Fonquernie Pol1ORCID,Albalad Jorge1ORCID,Price Jason R.2,Bloch Witold M.3ORCID,Evans Jack D.1ORCID,Doonan Christian J.1ORCID,Sumby Christopher J.1ORCID

Affiliation:

1. Centre for Advanced Nanomaterials and Department of Chemistry, School of Physics, Chemistry and Earth Sciences, The University of Adelaide Adelaide, SA 5005, Australia

2. ANSTO Melbourne, The Australian Synchrotron, 800 Blackburn Rd, Clayton, Vic 3168, Australia

3. College of Science & Engineering, Flinders University, Sturt Road, Bedford Park, SA 5042, Australia

Abstract

MOFs formed from 8-connecting nodes and 4-connecting linkers can have the flu, scu and csq topologies. Here we show design criteria for making the rare sqc topology and how topology can be used to generate distinct post-synthetic metalation sites.

Funder

Australian Research Council

Australian Government

Australian Institute of Nuclear Science and Engineering

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry

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