Topological control of metal–organic frameworks toward highly sensitive and selective detection of chromate and dichromate

Author:

Li Zi-Jian1ORCID,Ju Yu12,Wu Xiao-Ling1ORCID,Li Xiaoyun1,Qiu Jie3,Li Yongxin4,Zhang Zhi-Hui2ORCID,He Ming-Yang2ORCID,Zhang Linjuan1ORCID,Wang Jian-Qiang1ORCID,Lin Jian3ORCID

Affiliation:

1. Key Laboratory of Interfacial Physics and Technology, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai 201800, China

2. Jiangsu Key Laboratory of Advanced Catalytic Materials and Technology, Changzhou University, Changzhou 213164, China

3. School of Nuclear Science and Technology, Xi'an Jiaotong University, No. 28, West Xianning Road, Xi'an, 710049, P. R. China

4. Division of Chemistry and Biological Chemistry, School of Physical and Mathematical Sciences, Nanyang Technological University, 637371, Singapore

Abstract

A synthetic modulation approach has given rise to two topologically distinct thorium-based MOFs, whose polymorphism allows for elucidating how the structure of MOF, in isolation, influences the sensing efficacy of Cr(vi) oxyanions.

Funder

Chinese Academy of Sciences

K. C. Wong Education Foundation

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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