Bouncing off walls – widths of exit channels from shallow minima can dominate selectivity control-Reference-Cited by-同舟云学术

Bouncing off walls – widths of exit channels from shallow minima can dominate selectivity control

Published:2020 Issue:36 Volume:11 Page:9937-9944
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Bai Mengna¹²³⁴⁵,Feng Zhitao⁶⁷⁸⁹^ORCID,Li Jun¹²³⁴⁵^ORCID,Tantillo Dean J.⁶⁷⁸⁹^ORCID

Affiliation:

1. School of Chemistry and Chemical Engineering

2. Chongqing Key Laboratory of Theoretical and Computational Chemistry

3. Chongqing University

4. Chongqing

5. China

6. Department of Chemistry

7. University of California Davis

8. Davis

9. USA

Abstract

A selectivity model based on the widths of pathways to competing products, rather than barrier heights, is formulated for the butadiene + allyl cation reaction.

Funder

National Natural Science Foundation of China

China Scholarship Council

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04036C

Reference57 articles.

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4. Syntheses of Seven- and Five-Membered Rings from Allyl Cations

5. Preparation of a Bicyclic Analog of Qinghao (Artemisinic) Acid via a Lewis Acid Catalyzed Ionic Diels-Alder Reaction Involving a Hydroxy Diene and Cyclic Enone and Facile Conversion into (.+-.)-6,9-Desdimethylqinghaosu

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