Cyclobutane formation in the 2π + 2π cycloaddition of allyl and related cations to unactivated olefins. Evidence for the second step in the proposed mechanism of the ionic diels-alder reaction.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference34 articles.
1. Acid-catalyzed intramolecular "Diels-Alder" reactions. The cycloaddition of allyl cations to 1,3-dienes
2. Distinction between aminium cation radical and protic acid catalyzed Diels-Alder reactions
3. Control of regiospecificity in ionic Diels-Alder reactions. The use of allylic alcohols and allylic ethers as precursors of dienophilic allyl cations
4. Acrolein acetals as allyl cation precursors in the ionic Diels-Alder reaction
5. The low-temperature, ionic Diels-Alder addition of vinyl ortho esters to 1,3-dienes
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