Bouncing off walls – widths of exit channels from shallow minima can dominate selectivity control
Author:
Affiliation:
1. School of Chemistry and Chemical Engineering
2. Chongqing Key Laboratory of Theoretical and Computational Chemistry
3. Chongqing University
4. Chongqing
5. China
6. Department of Chemistry
7. University of California Davis
8. Davis
9. USA
Abstract
A selectivity model based on the widths of pathways to competing products, rather than barrier heights, is formulated for the butadiene + allyl cation reaction.
Funder
National Natural Science Foundation of China
China Scholarship Council
Division of Chemistry
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/2020/SC/D0SC04036C
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5. Preparation of a Bicyclic Analog of Qinghao (Artemisinic) Acid via a Lewis Acid Catalyzed Ionic Diels-Alder Reaction Involving a Hydroxy Diene and Cyclic Enone and Facile Conversion into (.+-.)-6,9-Desdimethylqinghaosu
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