Enantioselective deprotometalation of alkyl ferrocenecarboxylates using bimetallic bases

Author:

Dayaker Gandrath1,Erb William1ORCID,Hedidi Madani12,Chevallier Floris1ORCID,Blot Marielle1,Gros Philippe C.3ORCID,Hilmersson Göran4,Roisnel Thierry1ORCID,Dorcet Vincent1ORCID,Bentabed-Ababsa Ghenia2,Mongin Florence1ORCID

Affiliation:

1. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes) – UMR 6226, Rennes F-35000, France

2. Laboratoire de Synthèse Organique Appliquée, Faculté des Sciences Exactes et Appliquées, Université Oran1 Ahmed Ben Bella, BP 1524 El M’Naouer, Oran 31000, Algeria

3. Université de Lorraine, CNRS, L2CM, Nancy F-54000, France

4. Department of Chemistry and Molecular Biology, Göteborg University, Göteborg 41296, Sweden

Abstract

Our attempts to deprotometalate alkyl ferrocenecarboxylates enantioselectively by using chiral lithium–zinc or lithium–cadmium bases are reported.

Funder

Institut Universitaire de France

BASF

Agence Nationale de la Recherche

Université de Rennes 1

Direction Générale de la Recherche Scientifique et du Développement Technologique

Publisher

Royal Society of Chemistry (RSC)

Subject

Materials Chemistry,General Chemistry,Catalysis

Reference94 articles.

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3. A.Togni and T.Hayashi , Ferrocenes: Homogeneous Catalysis, Organic Synthesis, Materials Science , Wiley-VCH , Weinheim, Germany , 1995

4. L.-X.Dai and X.-L.Hou , Chiral Ferrocenes in Asymmetric Catalysis: Synthesis and Applications , Wiley-VCH , Weinheim , 2010

5. Recent advances in the synthesis, biological activities and various applications of ferrocene derivatives

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