Ferrocenephosphonates: Copper-Promoted Synthesis and Further Functionalization

Author:

Erb William1ORCID,Touil Soufiane2,Abaid Kmar12,Blot Marielle1,Roisnel Thierry1,Mongin Florence1ORCID

Affiliation:

1. Univ Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226

2. University of Carthage, Faculty of Sciences of Bizerte, Laboratory of Hetero-Organic Compounds and Nanostructured Materials (LR18ES11)

Abstract

AbstractFerrocenephosphonates make up an important class of organometallic derivatives with a wide range of useful applications in organic synthesis and coordination chemistry. Here, an approach to ferrocenephosphonates based on a copper-promoted Hirao coupling is reported. Further functionalizations based on regioselective deprotolithiation and both Negishi and Suzuki–Miyaura cross-coupling reactions are also described to reach original derivatives.

Funder

Université de Rennes 1

CNRS

Ministère de l’Enseignement Supérieur et de la Recherche Scientifique

European Regional Development Fund

Publisher

Georg Thieme Verlag KG

Subject

Organic Chemistry,Catalysis

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