Tuning of spin-crossover behavior in two cyano-bridged mixed-valence FeIII2FeII trinuclear complexes based on a TpR ligand-Reference-Cited by-同舟云学术

Tuning of spin-crossover behavior in two cyano-bridged mixed-valence FeIII2FeII trinuclear complexes based on a TpR ligand

Published:2022 Issue:2 Volume:9 Page:241-248
ISSN:2052-1553
Container-title:Inorganic Chemistry Frontiers
language:en
Short-container-title:Inorg. Chem. Front.

Author:

Sulaiman Arshia¹^ORCID,Jiang Yi-Zhan¹,Javed Mohammad Khurram¹^ORCID,Wu Shu-Qi²,Li Zhao-Yang¹^ORCID,Bu Xian-He¹³^ORCID

Affiliation:

1. School of Materials Science and Engineering, Nankai University, 38 Tongyan Road, Tianjin 300350, China

2. Institute for Materials Chemistry and Engineering & IRCCS, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka 819-0395, Japan

3. College of Chemistry, Nankai University, 94 Weijin Road, Tianjin 300071, China

Abstract

With the use of TpR derivatives, we have demonstrated the modulation in the SCO behavior in two analogous trinuclear complexes. Moreover, a change in the spin transition temperature via solvent loss is observed.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2022/QI/D1QI01086G

Reference50 articles.

1. Über die magnetische Susceptibilität der komplexen Verbindungen (II. Mitteil.).

2. M. A.Halcrow , Spin-crossover materials: properties and applications , John Wiley & Sons , 2013

3. K. S.Murray , The development of spin-crossover research , John Wiley & Sons Ltd , 2013 , pp. 1–54

4. Spin Crossover Probes Confer Multistability to Organic Conducting Polymers

5. Pressure and Temperature Spin Crossover Sensors with Optical Detection

Cited by 7 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Cyanide Addition to Diiron and Diruthenium Bis-Cyclopentadienyl Complexes with Bridging Hydrocarbyl Ligands;Inorganics;2024-05-28

2. Diverse Magnetic Properties of Two New Binuclear Complexes Affected by [FeN6] Octahedral Distortion: Two-Step Spin Crossover versus Antiferromagnetic Interactions;Magnetochemistry;2023-02-28

3. Tuning intramolecular electron transfer of cyanide bridged [Co₂Fe₂] squares through chemical modifications in solid and solution;Inorganic Chemistry Frontiers;2023

4. Synthesis and structural and spectroscopic properties of a cyanido-bridged mixed-valence compound [Fe–NC–Ru–CN–Fe];New Journal of Chemistry;2023

5. First crystal structure of an Fe(iii) anionic complex based on a pyruvic acid thiosemicarbazone ligand with Li⁺: synthesis, features of magnetic behavior and theoretical analysis;Dalton Transactions;2023