Dynamic solvent effects in radical–radical coupling reactions: an almost bottleable localised singlet diradical-Reference-Cited by-同舟云学术

Dynamic solvent effects in radical–radical coupling reactions: an almost bottleable localised singlet diradical

Published:2020 Issue:48 Volume:22 Page:27949-27954
ISSN:1463-9076
Container-title:Physical Chemistry Chemical Physics
language:en
Short-container-title:Phys. Chem. Chem. Phys.

Author:

Akisaka Rikuo¹²³⁴⁵^ORCID,Ohga Yasushi⁶⁷⁸⁹⁵,Abe Manabu¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Higashi-Hiroshima

5. Japan

6. Department of Integrated Science and Technology

7. Faculty of Science and Technology

8. Oita University

9. Oita 870-1192

Abstract

The lifetime of a localised singlet diradical with bulky substituents was extended using the dynamic solvent effect and reached an almost bottleable timescale of ∼2 s under extremely viscous conditions induced by high pressure.

Publisher

Royal Society of Chemistry (RSC)

Subject

Physical and Theoretical Chemistry,General Physics and Astronomy

Link

http://pubs.rsc.org/en/content/articlepdf/2020/CP/D0CP05235C

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