Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with π-single bonding character-Reference-Cited by-同舟云学术

Impact of the macrocyclic structure and dynamic solvent effect on the reactivity of a localised singlet diradicaloid with π-single bonding character

Published:2021 Issue:2 Volume:12 Page:613-625
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Wang Zhe¹²³⁴⁵^ORCID,Akisaka Rikuo¹²³⁴⁵^ORCID,Yabumoto Sohshi⁶⁷⁵,Nakagawa Tatsuo⁶⁷⁵,Hatano Sayaka¹²³⁴⁵,Abe Manabu¹²³⁴⁵^ORCID

Affiliation:

1. Department of Chemistry

2. Graduate School of Science

3. Hiroshima University

4. Hiroshima 739-8526

5. Japan

6. Unisoku Co., Ltd.

7. Osaka 573-0131

Abstract

An extremely long-lived localised singlet diradical with π-single bonding character is found in a macrocyclic structure that retards the radical–radical coupling reaction by the “stretch and solvent-dynamic effects”.

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/SC/D0SC05311B

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