A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties-Reference-Cited by-同舟云学术

A full set of iridium(iv) pyridine-alkoxide stereoisomers: highly geometry-dependent redox properties

Published:2017 Issue:2 Volume:8 Page:1642-1652
ISSN:2041-6520
Container-title:Chemical Science
language:en
Short-container-title:Chem. Sci.

Author:

Shopov Dimitar Y.¹²³⁴,Rudshteyn Benjamin¹²³⁴⁵,Campos Jesús¹²³⁴⁶,Vinyard David J.¹²³⁴⁷,Batista Victor S.¹²³⁴⁵,Brudvig Gary W.¹²³⁴⁵,Crabtree Robert H.¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. Yale University

3. New Haven

4. United States

5. Energy Sciences Institute

6. Instituto de Investigaciones Químicas (IIQ)

7. Department of Biological Sciences

Abstract

A complete series of Ir(iv) diastereomers coordinated with chlorides and bidentate pyridine-alkoxide ligands was prepared, revealing a number of significant unusual properties.

Funder

Division of Chemistry

Basic Energy Sciences

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2017/SC/C6SC03758E

Reference30 articles.

1. The Mechanism of Silicon−Hydrogen and Carbon−Hydrogen Bond Activation by Iridium(III): Production of a Silylene Complex and the First Direct Observation of Ir(III)/Ir(V) C−H Bond Oxidative Addition and Reductive Elimination

2. Isolated Ir(V) Boryl Complexes and Their Reactions with Hydrocarbons