Abstract
Artificial photosynthesis (AP) has been proved to be a promising way of alleviating global climate change and energy crisis. Among various materials for AP, molecular complexes play an important role due to their favorable efficiency, stability, and activity. As a result of its importance, the topic has been extensively reviewed, however, most of them paid attention to the designs and preparations of complexes and their water splitting mechanisms. In fact, ligands design and preparation also play an important role in metal complexes’ properties and catalysis performance. In this review, we focus on the ligands that are suitable for designing mononuclear catalysts for water splitting, providing a coherent discussion at the strategic level because of the availability of various activity studies for the selected complexes. Two main designing strategies for ligands in molecular catalysts, substituents modification and backbone construction, are discussed in detail in terms of their potentials for water splitting catalysts.
Cited by
3 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献